where S is the S-matrix or Scattering matrix that relates that relates the initial and final states of a physical system undergoing a scattering process.

and are the states at . Hence, they are non-interacting states and are the direct products of single-particle states, with definite on-shell momentum and polarisation , where i is the particle label.

On-shell momentum:

Metric convention:

We decompose the S-matrix as , so that we can separate out the interaction effects into a new matrix called the T-matrix.

LSZ Reduction Formula:

There are incoming and outgoing legs. Z is the wavefunction renormalisation.

Feynman DiagramsAmplitudes
- Not gauge invariant- Gauge invariant
- Have off-shell states in propagators- On-shell
- Hidden symmetries